Easiest and Hardest Overwatch Heroes to Master
From Easiest to Hardest ( [22] to [1] )

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[14] Roadhog
As a tank, Roadhog has important responsibilities of absorbing damage and pulling enemies out of their formation with his Chain Hook ability.  He mostly requires some decent aiming for the most part.

Scrap Gun:
Roadhog's Scrap Gun fires out very fast moving projectile pellets that takes an average amount of aiming and the learning curve isn't too steep.

Chain Hook:
Chain Hook (pulls in enemies with his Chain and Hook) is Roadhog's most difficult ability.  Aiming the Chain/Hook at enemies takes a lot of skill and you will need a lot of practice for that most likely.  There is a lot of other important things you need to learn about Chain Hook and how to get better at using it.

Take a Breather:
This ability fills up half of Roadhog's health (+300 HP), and it is a very easy ability to use, not much to it.

ULTIMATE Whole Hog:
Roadhog's ultimate is probably the second hardest thing to master after his Chain Hook.  When he uses Whole Hog, he becomes very vulnerable, so knowing when to use it will take some knowledge.  Once activated, it takes only a little bit of skill to maintain good control of it.