In the Middle Ages, both in the Islamic world and in Europe, agriculture was transformed with improved techniques and the diffusion of crop plants, including the introduction of sugar, rice, cotton and fruit trees such as the orange to Europe by way of Al-Andalus. After 1492, the Columbian exchange brought New World crops such as maize, potatoes, sweet potatoes and manioc to Europe, and Old World crops such as wheat, barley, rice and turnips, and livestock including horses, cattle, sheep and goats to the Americas. Irrigation, crop rotation, and fertilizers were introduced soon after the Neolithic Revolution and developed much further in the past 200 years, starting with the British Agricultural Revolution. Since 1900, agriculture in the developed nations, and to a lesser extent in the developing world, has seen large rises in productivity as human labour has been replaced by mechanization, and assisted by synthetic fertilizers, pesticides, and selective breeding. The Haber-Bosch method allowed the synthesis of ammonium nitrate fertilizer on an industrial scale, greatly increasing crop yields. Modern agriculture has raised political issues including water pollution, biofuels, genetically modified organisms, tariffs and farm subsidies.